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Design and Synthesis of New 1D and 2D R-isophthalic Acid-Based Coordination Polymers (R = Hydrogen or Bromine)

Design and Synthesis of New 1D and 2D R-isophthalic Acid-Based Coordination Polymers (R = Hydrogen or Bromine)

Ren Zhang, Qihan Gong, Thomas J Emge, Debasis Banerjee, Jing Li

Chimia (Aarau). 2013;67(6):393-6.

PMID: 23945098

Abstract:

Three new R-isophthalic acid-based (R = H or Br) coordination polymers have been designed and synthesized. By changing the N-containing ligand in the system, we are able to tune the dimensionality of coordination polymers from one-dimension (1D) to two-dimensions (2D) with the same basic building unit. Also, different metal ions can be incorporated into the same structures. Compound 1 [Cu(bipa)(py)2]·0.5(H2O) (H2bipa = 5-bromoisophthalic acid; py = pyridine) and compound 2 [Co(bipa)(py)2] are 1D chain structures. Compound 3 [Cu8(ipa)8(bpe)8]·2(bpe)·4(H2O) (bpe=1,2-bis(4-pyridyl)ethane) is a 2D layered structure.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP23351919	5-Bromoisophthalic acid		23351-91-9	Price

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