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Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} Tetra-Hydrate

Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} Tetra-Hydrate

Jian-Hua Guo

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1884.

PMID: 22199645

Abstract:

In the mol-ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa-hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN(3))-1-phenyl-propan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd-O distance,and the N atom of the second L ligand, forming the longer Cd-N distance, occupy axial positions with an N-Cd-O angle of 170.77 (7)°. Inter-molecular O-H⋯O hydrogen bonds exist between the lattice water mol-ecules and the acetate ions of adjacent mol-ecules, resulting in a two-dimensional supra-molecular structure.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP89759808	Cadmium acetate hydrate		89759-80-8	Price

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