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Di-μ-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}

Di-μ-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}

Christopher Goh, Zachary D Remillard, Andre P Martinez, Amanda C Keeley, Jerry P Jasinski

Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m691-2.

PMID: 22590172

Abstract:

In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C-H⋯π inter-actions feature in the crystal packing.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP500717237	Bis(9,9-dimethyl-9H-fluoren-7-yl)amine		500717-23-7	Price

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