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Di-( M- M- m)terphenyl-Embedded Decaphyrin and Its Bis-Rh(I) Complex

Mainak Das, B Adinarayana, M Murugavel, Subhashree Nayak, A Srinivasan

Org Lett. 2019 Apr 19;21(8):2867-2871.

PMID: 30958682

Abstract:

A new rectangular-shaped carbadecaphyrin was successfully synthesized by introducing a terphenylene unit ( m- m- m) in the macrocyclic core. The terphenylene moiety offers an open framework with multiple binding pockets to stabilize two Rh(I) ions in the core. The photophysical and structural studies reveal the non-aromatic character of the ligand and its bis-Rh(I) complex.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP92068 m-Terphenyl m-Terphenyl 92-06-8 Price
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