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Diacetatodi-tert-butyltin(IV)

Diacetatodi-tert-butyltin(IV)

Martin Reichelt, Hans Reuter

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 13;69(Pt 5):m254.

PMID: 23723767

Abstract:

The title compound, [Sn(C4H9)2(CH3COO)2], was synthesized in order to study the influence of large organic groups on the mol-ecular structure of diorganotin di-acetates. The title compound exhibits the same structure type as other diorganotin(IV) di-acetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this mol-ecular structure is expressed in two significant differences: tin-carbon bond lengths are much more longer than in the other di-acetates, as are the additional inter-actions of the acetate groups with the tin atom. Inter-molecular inter-actions are restricted to C-H⋯O ones similar to those in the other di-acetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP2800966	Tin(IV) acetate		2800-96-6	Price

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