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Dibromido(1,10-phenanthroline-κN,N')palladium(II)

Dibromido(1,10-phenanthroline-κN,N')palladium(II)

Kwang Ha

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m7.

PMID: 21579964

Abstract:

In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter-molecular π-π inter-actions between adjacent six-membered rings, the shortest centroid-centroid distance being 3.680 (4) Å. The nearly planar [maximum deviation 0.143 (2) Å] mol-ecules stack in columns parallel to (101) with a Pd⋯Pd distance of 4.8466 (9) Å.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP13444945	Palladium(II) bromide		13444-94-5	Price

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