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Dichlorido[1-(1-naphthyl-meth-yl)-3-(2-pyrid-yl)-1H-pyrazole-κN,N]palladium(II)

Dichlorido[1-(1-naphthyl-meth-yl)-3-(2-pyrid-yl)-1H-pyrazole-κN,N]palladium(II)

Chun-Sen Liu, Guang-Hui Sun, Liang-Qi Guo

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m69.

PMID: 21200638

Abstract:

In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid-yl)pyrazol-1-ylmeth-yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononuclear units form inter-molecular C-H⋯π inter-actions involving the benzene and pyridine rings of different L ligands and π-π stacking inter-actions between the pyrazolyl-pyridine and naphthalene rings of neighbouring L ligands, with a centroid-centroid separation of 3.522 (1) Å.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP141029314	N-(1-Naphthyl)-N-phenylmethacrylamide		141029-31-4	Price

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