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Dichloridobis[3-meth-oxy-methyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-κN,N]chromium(III) Chloride

Dichloridobis[3-meth-oxy-methyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-κN,N]chromium(III) Chloride

Xiaofei Jin, Zuoxiang Wang, Shouping Cao

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1492.

PMID: 22219745

Abstract:

In the title complex, [CrCl(2)(C(15)H(14)N(4)O)(2)]Cl, the Cr(III) atom is located on a twofold rotation axis and is coordinated by two N,N'-bidentate triazole derivatives and two chloride ions in a distorted octa-hedral CrN(2)N'(2)Cl(2) geometry. One of the two independent Cl(-) counter-anions sits on a special position (site symmetry [Formula: see text].) and is fully occupied, whereas the other is disordered around a twofold rotation axis over two positions in a 2:3 ratio.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP10025737	Chromium(III) chloride		10025-73-7	Price

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