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Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris-(pyridin-2-yl)-2-imidazoline-κ(3)N(2),N(3),N(4)]ytterbium(III) Chloride

Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris-(pyridin-2-yl)-2-imidazoline-κ(3)N(2),N(3),N(4)]ytterbium(III) Chloride

Alberto Baez-Castro, Herbert Höpfl, Miguel Parra-Hake, Adriana Cruz-Enriquez, Jose J Campos-Gaxiola

Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m815-6.

PMID: 22719359

Abstract:

In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions. Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP10361918	Ytterbium(III) chloride		10361-91-8	Price

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