Home
Resources
Publications
Dichloro[(6R,7S,8S,14S)-(-)-sparteine-kappa2N,N']mercury(II)

Dichloro[(6R,7S,8S,14S)-(-)-sparteine-kappa2N,N']mercury(II)

Sung-Nak Choi, Sang-Yub Kim, Hae-Wook Ryu, Yong-Min Lee

Acta Crystallogr C. 2005 Dec;61(Pt 12):m504-6.

PMID: 16330831

Abstract:

In the title compound, [HgCl2(C15H26N2)], the chiral alkaloid (6R,7S,8S,14S)-(-)-L-sparteine acts as a bidentate ligand, with two Cl- ligands occupying the remaining coordination sites, producing a distorted tetrahedron. The N-Hg-N plane is twisted by 81.1 (2) degrees from the Cl-Hg-Cl plane. The mid-point of the N...N line does not lie exactly on the Cl-Hg-Cl plane but is tilted towards one of the N atoms by 0.346 angstroms. Similarly, the mid-point of the Cl...Cl line is tilted toward one of the Cl atoms by 0.163 angstroms. The packing structure shows that the complex is stabilized by two interatomic Cl...H contacts involving both Cl atoms and the methylene or methine H atoms of the (-)-sparteine ligand.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP90391	(−)-Sparteine		90-39-1	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: