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Diiodido(1,10-phenanthroline-κN,N')platinum(II)

Diiodido(1,10-phenanthroline-κN,N')platinum(II)

Kwang Ha

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 16;66(Pt 1):m65.

PMID: 21579960

Abstract:

In the title complex, [PtI(2)(C(12)H(8)N(2))], the Pt(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two iodide ions. The nearly planar mol-ecules, with a maximum deviation of 0.170 (3) Å from the least-squares plane, are stacked in columns along the c axis with a Pt⋯Pt distance of 4.8510 (6) Å. In the column, π-π inter-actions between adjacent six-membered rings are present, the shortest centroid-centroid distance being 3.703 (5) Å.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7790398	Platinum(II) iodide		7790-39-8	Price

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