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Effect of Side Chain Functional Group on Interactions in Ionic Liquid Systems: Insights From Infinite Dilution Thermodynamic Data

Effect of Side Chain Functional Group on Interactions in Ionic Liquid Systems: Insights From Infinite Dilution Thermodynamic Data

Kamil Paduszyński, Marta Królikowska

J Phys Chem B. 2017 Nov 2;121(43):10133-10145.

PMID: 28976771

Abstract:

Measurements of infinite dilution activity coefficients of 48 molecular solutes (including alkanes, alkenes, alkynes, aromatics, ethers, alcohols, water, ketones, pyridine, thiophene, acetonitrile, and 1-nitropropane) in two ionic liquids (ILs), namely, 1-(2-hydroxyethyl)-3-methylimidazolium dicyanamide and 1-(2-chloroethyl)-3-methylimidazolium dicyanamide, are reported in the temperature range from T = 308.15 to 358.15 K. Comparative analysis of an effect of OH/Cl substitution of terminal carbon in side chains of imidazolium cations is presented and discussed in terms of different types of intermolecular forces acting between ILs and solutes. The new data also are confronted to those published previously for a "plain" counterpart of the studied ILs, namely, 1-ethyl-3-methylimidazolium dicyanamide. Infinite dilution capacity and selectivity of the studied ILs are presented to evaluate them as separating agents in extraction of aromatics from alkanes and sulfur compounds from alkanes. Three modeling approaches, namely, linear solvation energy relationship (LSER), regular solution theory, and conductor-like screening model for real solvents (COSMO-RS), are tested for their capabilities of capturing the substitution effects detected experimentally.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1186103478	1-(2-Hydroxyethyl)-3-methylimidazolium dicyanamide		1186103-47-8	Price

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