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Electrochemiluminescence Sensor for Melamine Based on a Ru(bpy)₃²⁺-doped Silica nanoparticles/carboxylic Acid Functionalized Multi-Walled Carbon nanotubes/Nafion Composite Film Modified Electrode

Electrochemiluminescence Sensor for Melamine Based on a Ru(bpy)₃²⁺-doped Silica nanoparticles/carboxylic Acid Functionalized Multi-Walled Carbon nanotubes/Nafion Composite Film Modified Electrode

Xiaomei Chen, Sai Lian, Ying Ma, Aihong Peng, Xiaotian Tian, Zhiyong Huang, Xi Chen

Talanta. 2016 Jan 1;146:844-50.

PMID: 26695338

Abstract:

In this work, a sensitive electrochemiluminescence (ECL) sensor for the determination of melamine (MEL) was developed based on a Ru(bpy)3(2+)-doped silica nanoparticles (RUDS)/carboxylic acid functionalized multi-walled carbon nanotubes (CMWCNTs)/Nafion composite film modified electrode. The homogeneous spherical RUDS were synthesized by a reverse microemulsion method. As Ru(bpy)3(2+) were encapsulated in the RUDS, Ru(bpy)3(2+) dropping from the modified electrode can be greatly prevented, which is helpful for obtaining a stable ECL signal. Moreover, to improve the conductivity of the film and promote the electron transfer rate on electrode surface, CMWCNTs with excellent electrical conductivity and large surface area were applied in the construction of the sensing film. As CMWCNTs acted as electron bridges making more Ru(bpy)3(2+) participate in the reaction, the ECL intensity was greatly enhanced. Under the optimum conditions, the relative ECL signal (△IECL) was proportional to the logarithmic MEL concentration ranging from 5×10(-13) to 1×10(-7) mol L(-1) with a detection limit of 1×10(-13) mol L(-1). To verify the reliability, the thus-fabricated ECL sensor was applied to determine the concentration of MEL in milk. Based on these investigations, the proposed ECL sensor exhibited good feasibility and high sensitivity for the determination of MEL, promising the applicability of this sensor in practical analysis.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS71726	Carbon nanotube, multi-walled, carboxylic acid functionalized			Price

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