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Enantioselective 1,4-addition of Cyclopropylboronic Acid Catalyzed by rhodium/chiral Diene Complexes

Ryosuke Takechi, Takahiro Nishimura

Chem Commun (Camb). 2015 May 18;51(40):8528-31.

PMID: 25892197

Abstract:

Rhodium-catalyzed asymmetric addition of cyclopropylboronic acids to electron-deficient alkenes such as alkenylsulfones, enones, enoates, and nitroalkenes proceeded to give high yields of the corresponding 1,4-addition products with high enantioselectivity.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP411235579 Cyclopropylboronic acid Cyclopropylboronic acid 411235-57-9 Price
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