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Equilibrium Data for the Cross-Metathesis of Methyl Oleate With Cinnamaldehyde

Pablo D Nieres, Andrés F Trasarti, Carlos R Apesteguía

Data Brief. 2018 Jul 31;20:190-195.

PMID: 30112434

Abstract:

Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch reactors, using different reactant molar ratios and the 2nd generation Ru Hoveyda-Grubbs complex as catalyst. Reaction mixtures at the equilibrium were analyzed by gas chromatography. Equilibrium constants were determined by assuming unitary activity coefficients for a cinnamaldehyde/methyl oleate equimolar ratio, and the validity of that approximation was evaluated by calculating the equilibrium conversions for different reactant molar ratios.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP112629-A Methyl oleate Methyl oleate 112-62-9 Price
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