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exo-1,7-Dimethyl-4-phenyl-10-oxa-4-aza-tri-cyclo-[5.2.1.0(2,6)]dec-8-ene-3,5-dione

Armando Pineda-Contreras, Oscar Fernando Vázquez-Vuelvas, Laura Edith Negrete-López, Héctor García-Ortega, Marcos Flores-Alamo

Acta Crystallogr Sect E Struct Rep Online. 2013 Nov 9;69(Pt 12):o1756.

PMID: 24454209

Abstract:

The title compound, C16H15NO3, consists of an oxabicycle fused to an N-phenyl-substituted pyrrolidine ring anti to the double bond, affording the exo isomer. In the oxabicycle system, the six-membered ring presents a boat conformation, while the heterocyclic rings show envelope conformations with the O atom projected out of the plane. In the crystal, adjacent mol-ecules are linked via weak C-H⋯O hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C-H⋯π inter-actions, forming two-dimensional networks lying parallel to the ac plane.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP75541832 Exo 1 Exo 1 75541-83-2 Price
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