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Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H(2)O(2)/Os(3)(CO)(12)/pyridine

Georgiy B Shul'pin, Yuriy N Kozlov, Lidia S Shul'pina, Alexander R Kudinov, Dalmo Mandelli

Inorg Chem. 2009 Nov 16;48(22):10480-2.

PMID: 19842662

Abstract:

Triosmium dodecacarbonyl catalyzes a very efficient oxidation of alkanes by H(2)O(2) in MeCN to afford alkyl hydroperoxides (primary products) as well as alcohols and ketones (aldehydes) at 60 degrees C if pyridine is added in a low concentration. Turnover numbers attain 60,000, and turnover frequencies are up to 24,000 h(-1).

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP15696409 Triosmium dodecacarbonyl Triosmium dodecacarbonyl 15696-40-9 Price
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