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Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials

Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials

Shuqin Chen, Jianmei Gao, Junyu Chang, Yanqi Li, Changxin Huangfu, Hu Meng, Yu Wang, Guangjie Xia, Liang Feng

ACS Appl Mater Interfaces. 2019 May 15;11(19):17513-17520.

PMID: 31016959

Abstract:

While a number of highly luminescent copper(I) halide based hybrid materials built on coordinate bonds (Cu-L; L = N, P, S-based ligands) have been obtained, the poor structural stability largely limited their commercialization. In contrast, according to the previous studies, the ionic structures (L-free) are more stable than those built on Cu-L coordinate bonds. However, the extremely weak emission hinders their optical applications. Herein, we report a tetra-alkylammonium-cation-induced strategy for the synthesis of stable and highly luminescent ionic CuBr-based hybrid materials. It is interesting to find that the tetra-alkylammonium cations with different chains could induce diverse CuBr-based anions. Moreover, most of these CuBr-based hybrids are highly luminescent, which makes them promising candidates as an alternative to phosphors and with potential applications in sensing.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7787704	Copper(I) bromide		7787-70-4	Price

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