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Far-infrared Terahertz Properties of L-cysteine and Its Hydrochloride Monohydrate

Guanhua Ren, Siqi Zong, Zhongjie Zhu, Chao Cheng, Ligang Chen, Lu Zhou, Jianbing Zhang, Liyuan Liu, Jiaguang Han, Hongwei Zhao

Spectrochim Acta A Mol Biomol Spectrosc. 2020 Jan 15;225:117476.

PMID: 31470346

Abstract:

As the building blocks of proteins, amino acids serve vital metabolic functions in addition to protein synthesis and thus attract enormous interest. Here we reported the far-infrared optical properties of L-cysteine (Lcys) and its hydrochloride monohydrate (LCHM) characterized by terahertz time-domain spectroscopy. The Lcys and LCHM exhibit quite distinct characteristics in the terahertz region due to diverse collective vibrations of the molecules, which is further confirmed by the solid-state density functional theory (DFT) calculations. The presented studies indicate that the intermolecular hydrogen bonds play a critical role in the far-infrared terahertz response of Lcys and LCHM.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7048046-B L-Cysteine hydrochloride monohydrate L-Cysteine hydrochloride monohydrate 7048-04-6 Price
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