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Formation of [Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- Via CS2 Insertion Into nickel(III) Hydride Containing [Ni(III)(H)(P(o-C6H3-3-SiMe3-2-S)3)]-

Formation of [Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]- Via CS2 Insertion Into nickel(III) Hydride Containing [Ni(III)(H)(P(o-C6H3-3-SiMe3-2-S)3)]-

Kuan-Ting Lai, Wei-Chieh Ho, Tzung-Wen Chiou, Wen-Feng Liaw

Inorg Chem. 2013 Apr 15;52(8):4151-3.

PMID: 23541028

Abstract:

Insertion of CS2 into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)3)] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)3] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe2CMe2O) in tetrahydrofuran at -80 °C via a metathesis reaction, readily affords [PPN][Ni(III)(κ(1)-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)] (2) featuring a κ(1)-S2CH moiety.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS793334	2-(4-fluoro-2-methylphenyl)4,4,5,5-tetramethyl-1,3,2-dioxaborolane			Price

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