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From Pincer to Paddlewheel: C-H and C-S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II)

From Pincer to Paddlewheel: C-H and C-S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II)

Partha Halder, Daniel J SantaLucia, Sungho V Park, John F Berry

Inorg Chem. 2019 Feb 18;58(4):2270-2274.

PMID: 30698431

Abstract:

The bis(2-pyridylthio)methanidopalladium(II) pincer complex (1), containing a Pd-C bond, was obtained from the reaction of bis(2-pyridylthio)methane (H2L) with palladium(II) acetate in toluene under reflux. When palladium(II) trifluoroacetate was used, H2L reacted to generate the tetrakis(pyridine-2-thiol)palladium(II) complex (2). Complex 2 was converted to a heterobimetallic palladium(II)-iron(II) paddlewheel complex (3) upon treatment with iron(II) triflate in the presence of a base in acetonitrile at room temperature.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP3094879	Iron(II) acetate		3094-87-9	Price
AP42196316	Palladium(II) trifluoroacetate		42196-31-6	Price

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