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Graphene-encapsulated Fe3O4 Nanoparticles With 3D Laminated Structure as Superior Anode in Lithium Ion Batteries

Graphene-encapsulated Fe3O4 Nanoparticles With 3D Laminated Structure as Superior Anode in Lithium Ion Batteries

Jia-Zhao Wang, Chao Zhong, David Wexler, Nurul Hayati Idris, Zhao-Xiang Wang, Li-Quan Chen, Hua-Kun Liu

Chemistry. 2011 Jan 10;17(2):661-7.

PMID: 21207587

Abstract:

Fe(3)O(4)-graphene composites with three-dimensional laminated structures have been synthesised by a simple in situ hydrothermal method. From field-emission and transmission electron microscopy results, the Fe(3)O(4) nanoparticles, around 3-15 nm in size, are highly encapsulated in a graphene nanosheet matrix. The reversible Li-cycling properties of Fe(3)O(4)-graphene have been evaluated by galvanostatic discharge-charge cycling, cyclic voltammetry and impedance spectroscopy. Results show that the Fe(3)O(4)-graphene nanocomposite with a graphene content of 38.0 wt % exhibits a stable capacity of about 650 mAh g(-1) with no noticeable fading for up to 100 cycles in the voltage range of 0.0-3.0 V. The superior performance of Fe(3)O(4)-graphene is clearly established by comparison of the results with those from bare Fe(3)O(4). The graphene nanosheets in the composite materials could act not only as lithium storage active materials, but also as an electronically conductive matrix to improve the electrochemical performance of Fe(3)O(4).

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS71750	Fe3O4/graphene nanocomposite			Price

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