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Heterodinuclear Fe(III)Zn(II)-bioinspired Complex Supported on 3-aminopropyl Silica. Efficient Hydrolysis of Phosphate Diester Bonds

Heterodinuclear Fe(III)Zn(II)-bioinspired Complex Supported on 3-aminopropyl Silica. Efficient Hydrolysis of Phosphate Diester Bonds

Clovis Piovezan, Rafael Jovito, Adailton J Bortoluzzi, Hernán Terenzi, Franciele L Fischer, Patricia C Severino, Claus T Pich, Gisele G Azzolini, Rosely A Peralta, Liane M Rossi, Ademir Neves

Inorg Chem. 2010 Mar 15;49(6):2580-2.

PMID: 20163108

Abstract:

Presented herein is the synthesis and characterization of a new Fe(III)Zn(II) complex containing a Fe(III)-bound phenolate with a carbonyl functional group, which was anchored to 3-aminopropyl-functionalized silica as the solid support. The catalytic efficiency of the immobilized catalyst in the hydrolysis of 2,4-bis(dinitrophenyl)phosphate is comparable to the homogeneous reaction, and the supported catalyst can be reused for subsequent diester hydrolysis reactions.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS761201	3-Aminopropyl functionalized silica			Price

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