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High Functional Nano Materials for Ophthalmic Lenses Containing Silicon 2,3-naphthalocyanine Bis(trihexylsilyloxide) and Silicon 2,9,16,23-tetra-tert-butyl-29H31 H-phthalocyanine Dihydroxide

High Functional Nano Materials for Ophthalmic Lenses Containing Silicon 2,3-naphthalocyanine Bis(trihexylsilyloxide) and Silicon 2,9,16,23-tetra-tert-butyl-29H31 H-phthalocyanine Dihydroxide

A-Young Sung, Tae-Hun Kim

J Nanosci Nanotechnol. 2014 Nov;14(11):8523-30.

PMID: 25958557

Abstract:

High functional ophthalmic lens materials, poly(HEMA-co-GMA)s were prepared by the copolymerization of HEMA, MMA, NVP, EDGMA and GMA in the presence of SiNc [silicon 2,3-naphthalocyanine bis(trihexylsilyloxide)] and SiPc (silicon 2,9,16,23-tetra-tert-butyl-29H31H-phthalocyanine dihydroxyde). Also, the physical and optical characteristics of the produced polymers were analyzed to investigate UV-blocking capabilities of these functional ophthalmic dyes and their applicability as materials for colored hydrogel contact lenses. For G_SN samples to which GMA was added to the Ref._SN combination, the transmittance for visible ray, UV-B and UV-A was in the range of 86.0-89.4%, 63.0-67.6% and 62.5-66.0% respectively. Also, for G_SP samples, the transmittance for visible ray, UV-B and UV-A was in the range of 85.2-87.0%, 70.0-72.6 and 68.0-70.2% respectively. The measurement of the spectral transmittance showed that both SiNc and SiPc absorbed a small amount of UV light, but the absorption pattern for UV light differed for each material. Based on the results, the addition of SiNc and SiPc to ophthalmic polymer materials can be used for various purposes in colored ophthalmic lens that are capable of offering protection from UV and infrared light without significant change of the physical properties.

Chemicals Related in the Paper:

Catalog Number	Product Name	CAS Number	Price
AP19333154	Silicon phthalocyanine dihydroxide	19333-15-4	Price
AP23627896	2,3-Naphthalocyanine	23627-89-6	Price
AP85214706	Silicon 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine dihydroxide	85214-70-6	Price

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