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Highly Fluorescent pyreno[2,1-b]pyrroles: First Syntheses, Crystal Structure, and Intriguing Photophysical Properties

Srinivasan Selvi, Shih-Chieh Pu, Yi-Ming Cheng, Jim-Min Fang, Pi-Tai Chou

J Org Chem. 2004 Oct 1;69(20):6674-8.

PMID: 15387589

Abstract:

A series of pyrrole analogues of benzo[a]pyrene have been synthesized in which pyreno[2,1-b]pyrrole exhibits highly fluorescent properties in solution as well as in crystalline form even possessing strong pi-pi stacking. The pi-stacking-induced fluorescence spectral changes lead to future applications such as molecular recognition feasible upon chemical modification.

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