0

Homogeneously-catalysed Hydrogen release/storage Using the 2-methylindole/2-methylindoline LOHC System in Molten Salt-Organic Biphasic Reaction Systems

Alexander Søgaard, Marlene Scheuermeyer, Andreas Bösmann, Peter Wasserscheid, Anders Riisager

Chem Commun (Camb). 2019 Feb 12;55(14):2046-2049.

PMID: 30687857

Abstract:

Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid-liquid biphasic reaction system with molten [PPh4][NTf2] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP95205 2-Methylindole 2-Methylindole 95-20-5 Price
qrcode