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Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex

Christopher A Endicott, Herbert L Strauss, Chambers C Hughes, Dirk Trauner

J Phys Chem A. 2005 Sep 1;109(34):7714-7.

PMID: 16834146

Abstract:

The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethyl-phenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP13774817 Borane-ammonia complex Borane-ammonia complex 13774-81-7 Price
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