Home
Resources
Publications
Iron Chloride Catalysed PCDD/F-formation: Experiments and PCDD/F-signatures

Iron Chloride Catalysed PCDD/F-formation: Experiments and PCDD/F-signatures

Mengmei Zhang, Alfons Buekens, Siyuan Ma, Xiaodong Li

Chemosphere. 2018 Jan;191:72-80.

PMID: 29031055

Abstract:

Iron chloride is often cited as catalyst of PCDD/F-formation, together with copper chloride. Conversely, iron chloride catalysis has been less studied during de novo tests. This paper presents such de novo test data, derived from model fly ash incorporating iron (III) chloride and established over a vast range of temperature and oxygen concentration in the gas phase. Both PCDD/F-output and its signature are extensively characterised, including homologue and congener profiles. For the first time, a complete isomer-specific analysis is systematically established, for all samples. Special attention is paid to the chlorophenols route PCDD/F, to the 2,3,7,8-substituted congeners, and to their relationship and antagonism.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP15742388	Pentaamminechloroiridium(III) chloride		15742-38-8	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: