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Magnetic Dynamics of a Neodymium(III) Single-Ion Magnet

Yan-Cong Chen, Xin-Shuo Huang, Jun-Liang Liu, Ming-Liang Tong

Inorg Chem. 2018 Sep 17;57(18):11782-11787.

PMID: 30160953

Abstract:

Slow relaxation of magnetization is observed in a neodymium(III) single-ion magnet based on phosphine oxide, which successfully extends our pentagonal bipyramidal family to light lanthanides. Comprehensive magnetic characterizations reveal that the magnetic dynamics follow the power law that corresponds to a Raman process, despite an energy splitting of 207 cm-1 evidenced by the ab initio calculation. Compared with a similar complex, the magnetic dynamics and magneto-structural correlations are clarified, providing deeper insight into the pursuit of promising light lanthanide single-molecule magnets.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1313979 Neodymium(III) oxide Neodymium(III) oxide 1313-97-9 Price
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