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Mobility of Chromium in Sediments Dominated by Macrophytes and Cyanobacteria in Different Zones of Lake Taihu

Mobility of Chromium in Sediments Dominated by Macrophytes and Cyanobacteria in Different Zones of Lake Taihu

Xianfang Fan, Shiming Ding, Musong Chen, Shuaishuai Gao, Zhen Fu, Mengdan Gong, Yan Wang, Chaosheng Zhang

Sci Total Environ. 2019 May 20;666:994-1002.

PMID: 30970505

Abstract:

To study the mechanisms of chromium (Cr) mobilization in sediments of lakes with different ecotypes, seasonal sampling was performed in the macrophyte-dominated East Taihu (MDET) and cyanobacteria-dominated Meiliang Bay (CDMB) in Lake Taihu. Concentrations of labile Cr(VI) and dissolved Cr were assessed using diffusive gradients in thin films (DGT) and high-resolution dialysis passive sampling devices, respectively. Results indicated that in pore water the dissolved Cr concentrations and in sediments total Cr and Cr fractions concentrations (dissolved, exchangeable and carbonate fraction (F1), Fe-Mn oxide fraction (F2), organic/sulfide fraction (F3)) were lower in MDET than in CDMB. However, the highly toxic DGT-labile Cr(VI) concentrations were higher in MDET sediments than in CDMB sediments. In the two lake zones, the seasonal variations in concentrations of dissolved Cr and DGT-labile Cr(VI) were significant, while total Cr and Cr fractions showed negligible changes (except F1 fraction). In summer, the high mobility of dissolved Cr (MDET: 103.42±10.82μg/L; CDMB: 108.99±4.24μg/L) were mainly caused by dissolved organic matter complexing with Cr(III). In winter the high mobility of dissolved Cr (MDET: 100.27±22.04μg/L; CDMB: 102.01±8.81μg/L) and DGT-labile Cr(VI) (MDET: 28.26±3.73μg/L; CDLZ: 25.82±2.26μg/L) were primarily caused by the oxidization of Cr (III) by Mn(III/IV) oxides. This study establishes the mechanisms for seasonal variation of Cr mobilization in different lake ecological zones, highlighting the urgent need for remediation of Cr pollution, especially in macrophyte-dominated lake zones.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AS2121462	Aquatic plant (Cr)			Price

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