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Monomeric organoantimony(III) Sulphide and Selenide With Terminal Sb-E Bond (E = S, Se). Synthesis, Structure and Theoretical Consideration

Petr Šimon, Roman Jambor, Aleš Růžička, Antonín Lyčka, Frank De Proft, Libor Dostál

Dalton Trans. 2012 May 7;41(17):5140-3.

PMID: 22441678

Abstract:

NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1315055 Antimony(III) selenide Antimony(III) selenide 1315-05-5 Price
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