Home
Resources
Publications
Myths and reality of HPbI 3 in halide perovskite solar cells

Myths and reality of HPbI 3 in halide perovskite solar cells

Weijun Ke, Ioannis Spanopoulos, Constantinos C Stoumpos, Mercouri G Kanatzidis

Nat Commun. 2018 Nov 14;9(1):4785.

PMID: 30429470

Abstract:

All-inorganic perovskites have a special place in halide perovskite family because of their potential for better stability. However, the representative cesium lead iodide (CsPbI3) is metastable and spontaneously converts to the non-perovskite structure at room temperature. Here, we demonstrate that what appears to be all-inorganic CsPbI3 stabilized in its perovskite form using the purported intermediate known as hydrogen lead iodide (HPbI3) is, in fact, the hybrid perovskite cesium dimethylammonium lead iodide (Cs1-xDMAxPbI3, x = 0.2 to 0.5). Thus, many of the reported all-inorganic perovskites are actually still hybrid organic-inorganic perovskites, as strongly evidenced by a wide battery of experimental techniques presented here. Solar cells based on the representative composition Cs0.7DMA0.3PbI3 can achieve an average power conversion efficiency of 9.27 ± 1.28% (max 12.62%). These results provide an alternative angle to look at previous results pertaining all-inorganic CsPbI3 while the DMA cation is now revealed as an alternative A site cation.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP51066741	Dimethylammonium iodide		51066-74-1	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: