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N,N',N''-Tricyclo-hexyl-guanidinium Iodide

N,N',N''-Tricyclo-hexyl-guanidinium Iodide

Farouq F Said, Basem F Ali, Darrin Richeson

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3467.

PMID: 22199942

Abstract:

In the title compound, C(19)H(36)N(3) (+)·I(-), the orientation of the cyclo-hexyl rings around the planar (sum of N-C-N angles = 360°) CN(3) (+) unit produces steric hindrance around the N-H groups. As a consequence of this particular orientation of the tricyclo-hexyl-guanidinium cation (hereafter denoted CHGH(+)), hydrogen bonding is restricted to classical N-H⋯I and non-clasical (cyclo-hex-yl)C-H⋯I hydrogen bonds. The propeller CHGH(+) cation and the oriented hydrogen-bonding interactions lead to a three-dimensional supra-molecular structure.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP19227704	Guanidinium iodide		19227-70-4	Price

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