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N-Phenylated N-Heteroacenes: Synthesis, Structures, and Properties

N-Phenylated N-Heteroacenes: Synthesis, Structures, and Properties

Xiao Gu, Bowen Shan, Zikai He, Qian Miao

Chempluschem. 2017 Jul;82(7):1034-1038.

PMID: 31961616

Abstract:

Herein, two novel N-phenylated N-heteroacenes (1 and 2) are reported, along with details of their synthesis, structures, and properties. Compound 1 is a N-hetero analogue of rubrene, but differs from rubrene by having a bent backbone and behaving as an insulator in the solid state owing to the lack of π-π interactions. Compound 2 is a N-hetero analogue of 6,13-diphenylpentacene (DPP) with essentially the same molecular geometry and crystal packing as DPP, but exhibiting a field effect mobility higher than that of DPP by two orders of magnitude.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP76727112	6,13-Diphenylpentacene		76727-11-2	Price

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