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New Photophysical Insights in Noncovalent Interaction Between Fulleropyrrolidine and a Series of Zincphthalocyanines

New Photophysical Insights in Noncovalent Interaction Between Fulleropyrrolidine and a Series of Zincphthalocyanines

Anamika Ray, Kotni Santhosh, Sumanta Bhattacharya

J Phys Chem A. 2011 Sep 8;115(35):9929-40.

PMID: 21774489

Abstract:

The present article reports, for the first time, the photophysical aspects of noncovalent interaction of a fullerene derivative, namely, C(60) pyrrolidine tris-acid ethyl ester (PyC(60)) with a series of zincphthalocyanines, for example, underivatized zincphthalocyanine (1), zinc-1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine (2), and zinc-2,3,9,10,16,17,23,24-octakis-(octyloxy)-29H,31H-phthalocyanine (3) in toluene. Ground state electronic interaction of PyC(60) with 1, 2 and 3 has been evidenced from the observation of well-defined charge transfer (CT) absorption bands in the visible region. Utilizing the CT transition energy, vertical electron affinity (E(A)(v)) of PyC(60) is determined. Steady state fluorescence experiment enables us to determine the value of binding constant (K) in the magnitude of 2.60 × 10(4) dm(3)·mol(-1), 2.20 × 10(4) dm(3)·mol(-1), and 1.27 × 10(4) dm(3)·mol(-1) for the noncovalent complexes of PyC(60) with 1, 2, and 3, respectively. K values of PyC(60)-ZnPc complexes suggest that PyC(60) is incapable of discriminating between 1, 2, and 3 in solution. Lifetime experiment signifies the importance of static quenching phenomenon for our presently investigated supramolecules and it yields larger magnitude of charge separated rate constant for the PyC(60)-1 species in toluene. Photoinduced energy transfer between PyC(60) and ZnPc derivatives, namely, 1, 2, and 3, in toluene, has been evidenced with nanosecond laser photolysis method by observing the transient absorption bands in the visible region; transient absorption studies establish that energy transfer from (T)PyC(60)* to the ZnPc occurs predominantly, as confirmed by the consecutive appearance of the triplet states of PyC(60). Theoretical calculations at semiempirical level (PM3) evoke the single projection geometric structures for the PyC(60)-ZnPc systems in vacuo, which also proves that interaction between PyC(60) and ZnPc is governed by the electrostatic mechanism rather than dispersive forces associated with π-π interaction.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP119457817	2,3,9,10,16,17,23,24-Octakis(octyloxy)-29H,31H-phthalocyanine		119457-81-7	Price
AP261504181	Zinc 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine		261504-18-1	Price

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