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Oxidative Metabolites of Lycopene and γ-carotene in Gac (Momordica Cochinchinensis)

Takashi Maoka, Yumiko Yamano, Akimori Wada, Tetsuji Etho, Yukimasa Terada, Harukuni Tokuda, Hoyoku Nishino

J Agric Food Chem. 2015 Feb 11;63(5):1622-30.

PMID: 25633727

Abstract:

Three new oxidative metabolites of lycopenes, (erythro)-lycopene-5,6-diol, (threo)-lycopene-5,6-diol, and 1,16-dehydro-2,6-cyclolycopene-5-ol B, and four new oxidative metabolites of γ-carotenes, 2',6'-cyclo-γ-carotene-1',5'-diol A, 2',6'-cyclo-γ-carotene-1',5'-diol B, (erythro)-γ-carotene-5,6-diol, and (threo)-γ-carotene-5,6-diol, were isolated as minor components from the aril of gac, Momordica cochinchinensis. These structures were determined on the basis of spectroscopic data, and some of them were compared to the structures of synthetic samples. Furthermore, the oxidative metabolic conversion pathways of lycopene and γ-carotene were discussed.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP472935 γ-Carotene γ-Carotene 472-93-5 Price
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