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Oxygen-doped Nanodiamonds: Synthesis and Functionalizations

Andrey A Fokin, Tatyana S Zhuk, Alexander E Pashenko, Pavlo O Dral, Pavel A Gunchenko, Jeremy E P Dahl, Robert M K Carlson, Tatyana V Koso, Michael Serafin, Peter R Schreiner

Org Lett. 2009 Jul 16;11(14):3068-71.

PMID: 19586063

Abstract:

Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP10377589 Magnesium iodide Magnesium iodide 10377-58-9 Price
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