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Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl](μ-α-oxido-benzyl-idene-1:2κO:C)titanium(IV)tungsten(0)

Catharine Esterhuysen, I B Jacques Nel, Matthias W Esterhuysen, Stephanie Cronje

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):m1534.

PMID: 21581149

Abstract:

The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP13470138 Tungsten(IV) chloride Tungsten(IV) chloride 13470-13-8 Price
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