Home
Resources
Publications
Penta-cyclo-[9.3.1.1(2,6).1(4,8).1(9,13)]octa-deca-1(2),8(9)-diene

Penta-cyclo-[9.3.1.1(2,6).1(4,8).1(9,13)]octa-deca-1(2),8(9)-diene

Savvas Ioannou, Eleni Moushi

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2150.

PMID: 22798823

Abstract:

The title compound, C(18)H(24), was the main product of thermolysis of noradamantene dimer (hepta-cyclo-[9.3.1.1(2,6).1(4,8).1(9,13).0(1,9).0(2,8)]octa-deca-ne). The crystal structure was determined to prove that the thermolysis product of noradamantene dimer is favored by stretch release due to ring opening of the four-membered ring. The bond length of the quaternary C atoms of the starting material was calculated as 1.6 Å, enlarged in comparison to other single bonds. After the rearrangement, the stretch release of the above carbons leads to an increase of the distance between them (2.824 Å) with respect to the crystallographic data.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP134179401	13,13,14,14-Tetramethyl-3,6,9,12-tetraoxa-13-sila-1-pentadecanol		134179-40-1	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: