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Photo-Induced Doping in a Graphene Field-Effect Transistor With Inkjet-Printed Organic Semiconducting Molecules

Photo-Induced Doping in a Graphene Field-Effect Transistor With Inkjet-Printed Organic Semiconducting Molecules

Nikita Nekrasov, Dmitry Kireev, Nejra Omerović, Aleksei Emelianov, Ivan Bobrinetskiy

Nanomaterials (Basel). 2019 Dec 10;9(12):1753.

PMID: 31835474

Abstract:

In this work, we report a novel method of maskless doping of a graphene channel in a field-effect transistor configuration by local inkjet printing of organic semiconducting molecules. The graphene-based transistor was fabricated via large-scale technology, allowing for upscaling electronic device fabrication and lowering the device's cost. The altering of the functionalization of graphene was performed through local inkjet printing of N,N'-Dihexyl-3,4,9,10-perylenedicarboximide (PDI-C6) semiconducting molecules' ink. We demonstrated the high resolution (about 50 µm) and accurate printing of organic ink on bare chemical vapor deposited (CVD) graphene. PDI-C6 forms nanocrystals onto the graphene's surface and transfers charges via π-π stacking to graphene. While the doping from organic molecules was compensated by oxygen molecules under normal conditions, we demonstrated the photoinduced current generation at the PDI-C6/graphene junction with ambient light, a 470 nm diode, and 532 nm laser sources. The local (in the scale of 1 µm) photoresponse of 0.5 A/W was demonstrated at a low laser power density. The methods we developed open the way for local functionalization of an on-chip array of graphene by inkjet printing of different semiconducting organic molecules for photonics and electronics.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP76372753	N,N′-Dipentyl-3,4,9,10-perylenedicarboximide		76372-75-3	Price

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