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Photocatalytic C-C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

Jing-Jing Guo, Anhua Hu, Yilin Chen, Jianfeng Sun, Haoming Tang, Zhiwei Zuo

Angew Chem Int Ed Engl. 2016 Dec 5;55(49):15319-15322.

PMID: 27862775

Abstract:

A general strategy for the cleavage and amination of C-C bonds of cycloalkanols has been achieved through visible-light-induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C-C bond cleavage and functionalization of unstrained secondary cycloalkanols.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7790865 Cerium(III) chloride Cerium(III) chloride 7790-86-5 Price
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