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Photodegradation of Pb-3,4-dihydroxybenzoic Acid Complex Under UV Light Illumination

Xuefeng Hu, Wei Qin

Water Sci Technol. 2012;65(5):948-53.

PMID: 22339032

Abstract:

The degradation of 3,4-dihydroxybenzoic acid (3,4-DHBA) in the presence and absence of Pb(2+) under UV illumination was studied. Addition of Pb(2+) caused the formation of precipitate during photoreaction when the solution pH was higher than 6. The presence of Pb(2+) remarkably inhibited the degradation of 3,4-DHBA and its photodegradation intermediates, while complexation of 3,4-DHBA and its photodegradation intermediates with Pb(2+) decreased the free Pb(2+) in aqueous solutions. Molecular oxygen played an important role in photodegradation of 3,4-DHBA in the presence of Pb(2+). UV-Vis spectroscopy was used to investigate the interaction between Pb(2+) and 3,4-DHBA at different pH conditions, and FT-IR was used to characterize the precipitate formed during photoreaction. The mineralization of 3,4-DHBA was investigate by total organic carbon analysis.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP99503-A 3,4-Dihydroxybenzoic acid 3,4-Dihydroxybenzoic acid 99-50-3 Price
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