0

Photorefractivity of poly-N-vinylindole-based Materials as Compared With That of poly-N-vinylcarbazole-based Blends

Marco Angiuli, Francesco Ciardelli, Arturo Colligiani, Francesco Greco, Annalisa Romano, Giacomo Ruggeri, Elpidio Tombari

Appl Opt. 2006 Oct 20;45(30):7928-37.

PMID: 17068530

Abstract:

The asymmetric two-beam coupling technique has been employed to measure the photorefractivity of thin films of polymer blends containing 2,5-dimethyl-4-(p-nitrophenylazo)anisole as the nonlinear optical component. Poly-(1-vinylindole) and poly-(2,3-dimethyl-1-vinylindole) were the photoconductive polymer counterparts. The values of the photorefractivity are reported. It appears that they are comparable with those of similar blends based on the well-known poly-(9-vinylcarbazole) (PVK), here considered as a reference standard. Careful differential scanning calorimetry analyses have been accomplished on the different blends taken into account to rationalize the significantly longer shelf lifetime of the indolyl-based films with respect to the PVK-based blends.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP25067598 Poly(9-vinylcarbazole) Poly(9-vinylcarbazole) 25067-59-8 Price
qrcode