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Plasma-induced, Nitrogen-Doped Graphene-Based Aerogels for High-Performance Supercapacitors

Xue-Yu Zhang, Shi-Han Sun, Xiao-Juan Sun, Yan-Rong Zhao, Li Chen, Yue Yang, Wei Lü, Da-Bing Li

Light Sci Appl. 2016 Oct 7;5(10):e16130.

PMID: 30167120

Abstract:

Commonly used energy storage devices include stacked layers of active materials on two-dimensional sheets, and the limited specific surface area restricts the further development of energy storage. Three-dimensional (3D) structures with high specific surface areas would improve device performance. Herein, we present a novel procedure to fabricate macroscopic, high-quality, nitrogen-doped, 3D graphene/nanoparticle aerogels. The procedure includes vacuum filtration, freeze-drying, and plasma treatment, which can be further expanded for large-scale production of nitrogen-doped, graphene-based aerogels. The behavior of the supercapacitor is investigated using a typical nitrogen-doped graphene/Fe3O4 nanoparticle 3D structure (NG/Fe3O4). Compared with 3D graphene/Fe3O4 structures prepared by the traditional hydrothermal method, the NG/Fe3O4 supercapacitor prepared by the present method has a 153% improvement in specific capacitance, and there is no obvious decrease in specific capacitance after 1000 cycles. The present work provides a new and facile method to produce large-scale, 3D, graphene-based materials with high specific capacitance for energy storage.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
LS76144 Nitrogen-doped graphene Nitrogen-doped graphene Price
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