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Poly[(μ(6)-benzene-1,2,4,5-tetra-carboxyl-ato)bis-(1,10-phenanthroline-κN,N')dimanganese(II)]

Poly[(μ(6)-benzene-1,2,4,5-tetra-carboxyl-ato)bis-(1,10-phenanthroline-κN,N')dimanganese(II)]

Xin-Dong Jiang, Xiu-Bing Li, Bai-Wang Sun

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):m922-3.

PMID: 21202779

Abstract:

The title polymeric compound, [Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2)](n), was obtained by the reaction of manganese(II) chloride tetra-hydrate with benzene-1,2,4,5-tetra-carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa-hedral geometry by two N atoms from one 1,10-phenanthroline ligand and four O atoms [Mn-O = 2.116 (2)-2.237 (2) Å] from three bta(4-) ligands, which also act as bridging groups between the Mn(2+) ions.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP73913061	Manganese(II) chloride hydrate		73913-06-1	Price

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