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Poly(9,9'-spirobifluorene-manganese Porphyrin): A New Catalytic Material for Oxidation of Alkenes by Iodobenzene Diacetate and Iodosylbenzene

Cyril Poriel, Yann Ferrand, Paul le Maux, Joëlle Raul-Berthelot, Gerard Simonneaux

Chem Commun (Camb). 2003 May 7;(9):1104-5.

PMID: 12772924

Abstract:

Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly(9,9'-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP159660 9,9′-Spirobifluorene 9,9′-Spirobifluorene 159-66-0 Price
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