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Production of (+)-globulol Needle Crystals on the Surface Mycelium of Quambalaria Cyanescens

E Stodůlková, M Sulc, I Císarová, P Novák, M Kolarík, M Flieger

Folia Microbiol (Praha). 2008;53(1):15-22.

PMID: 18481213

Abstract:

The structure of unique colorless needle crystals growing from the surface mycelium of the basidiomycete Quambalaria cyanescens and identified as (+)-globulol was followed by mass spectrometry, X-ray diffraction, and polarimetry. The mechanism of (+)-globulol fragmentation is proposed based on collision induced dissociation mass spectrometry. X-Ray analysis revealed that crystal packing is governed by hydrogen bond O-H.....O connecting the molecules into an infinite helix along a 3-fold screw axis propagating along the longest dimension of the needle crystal (c-axis of the unit cell). The X-ray diffraction data correspond well with the proposed structure determined by mass spectrometry.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP489418 (−)-Globulol (−)-Globulol 489-41-8 Price
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