Home
Resources
Publications
(R)-2-Methyl-5-[(R)-2,4,4,4-tetra-chloro-butan-2-yl]cyclo-hex-2-enone

(R)-2-Methyl-5-[(R)-2,4,4,4-tetra-chloro-butan-2-yl]cyclo-hex-2-enone

Brahim Boualy, Mohamed Anouar Harrad, Larbi El Firdoussi, Mustapha Ait Ali, Helen Stoeckli-Evans

Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):o2451-2.

PMID: 22904896

Abstract:

The title compound, C(11)H(14)Cl(4)O, was efficiently synthesized by atom-transfer radical addition between (R)-carvone and tetra-chloro-methane. In the mol-ecule, both chiral centres are of the absolute configuration R. The cyclo-hex-2-enone ring has an envelope conformation with the chiral C atom displaced by 0.633 (2) Å from the mean plane through the other five C atoms [maximum deviation = 0.036 (2) Å]. In the crystal, mol-ecules are linked via C-H⋯O inter-actions, leading to the formation of helical chains propagating along [100].

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP6485401	(−)-Carvone		6485-40-1	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: