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Radical Reaction of [60]fullerene With Phosphorus Compounds Mediated by manganese(III) Acetate

Radical Reaction of [60]fullerene With Phosphorus Compounds Mediated by manganese(III) Acetate

Guan-Wu Wang, Cong-Zhou Wang, Jian-Ping Zou

J Org Chem. 2011 Aug 5;76(15):6088-94.

PMID: 21671619

Abstract:

Radical reaction of [60]fullerene with phosphonates or phosphine oxide mediated by manganese(III) acetate dihydrate in chlorobenzene under three different conditions afforded three different types of phosphorylated fullerenes: singly bonded fullerene dimers 2, hydrophosphorylated fullerenes 3, and acetoxylated fullerene derivatives 4. In addition, interconversions among the three types of phosphorylated fullerene derivatives have also been investigated. A possible reaction mechanism was proposed to explain experimental results.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP19513054	Manganese(III) acetate dihydrate		19513-05-4	Price

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