Home
Resources
Publications
Radical Reactions of [60]fullerene Mediated by manganese(III) Acetate Dihydrate

Radical Reactions of [60]fullerene Mediated by manganese(III) Acetate Dihydrate

Guan-Wu Wang, Fa-Bao Li

J Nanosci Nanotechnol. Apr-May 2007;7(4-5):1162-75.

PMID: 17450885

Abstract:

Mn(OAc)3 x 2H2O is an excellent reagent to promote free radical reactions of C60. C60 reacted with various methylene active compounds, methyl ketones, beta-enamino carbonyl compounds, carboxylic acid derivatives, and diallylamines in the presence of Mn(OAc)3 x 2H2O to afford singly-bonded fullerene dimers, 1,4-bisadducts and 1,16-bisadducts of C60, C60-fused dihydrofuran derivatives, methanofullerenes, C60-fused pyrroline derivatives, C60-fused lactone derivatives, and C60-fused pyrrolidine derivatives. Mn(OAc)3 x 2H2O was successfully employed to transform ArC60-H into ArC60-OAc.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP19513054	Manganese(III) acetate dihydrate		19513-05-4	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: